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Creators/Authors contains: "Çallıoǧlu, Şafak"

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  1. ; ; (, Langmuir)
    Fluid−fluid interfaces are an attractive platform for self-assembling nanoparticles into low-dimensional materials. In this Perspective, we review recent developments in the use of interfaces to direct the assembly of spherical and anisotropic nanoparticles into diverse and sophisticated architectures. We illustrate how nanoparticle clusters, strings, networks, superlattices, chiral lattices, and quasicrystals can be self-assembled by harnessing the frustration between interfacial and interparticle forces. We highlight the role of polymeric ligands attached to the surface of nanoparticles in modulating assembly behavior by directly altering particle−fluid and particle−particle interactions or by deforming at interfaces and junctions between particles. We conclude by providing a roadmap of key questions and opportunities in this exciting field of interfacial assembly. 
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